CdTiO₃ nanoparticles were synthesized by solid-state reaction technique. X-ray diffraction (XRD) confirms the formation of rhombohedral CdTiO₃ nanoparticles and scanning electron microscopy (SEM) shows the irregularly shaped nanoparticles. The ac conductivity data was fitted using Jonscher’s power law to find the frequency exponent "s". Correlated barrier hopping (CBH) is found to be prevailing conduction mechanism from 300 K to 160 K. The density of states (DOS) calculated by applying CBH model lie in the range of 2.89 x 10²⁰ eV^-1cm^-3 to 2.96 x 10²¹ eV^-1cm^-3. The calculated minimum hopping distance (R_min) was 2.13 x 10^-9 m. The low values of tangent loss (< 1) at all temperatures suggest CdTiO₃ as a potential material in electrical devices with low energy losses. The shifting of maxima towards higher frequencies with the decrease in temperature in imaginary modulus plots suggests the thermally triggered hopping process in CdTiO₃ nanoparticles. The modulus studies confirm that hopping is the dominant conduction mechanism in CdTiO₃ nanoparticles as suggested by ac conductivity studies